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Volatiles from the tropical ascomycete (Hypoxylaceae, Xylariales).
Wang, Tao Mohr, Kathrin I Stadler, Marc Dickschat, Jeroen S
Wang, Tao
Mohr, Kathrin I
Stadler, Marc
Dickschat, Jeroen S
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2018-01-01
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Abstract
The volatiles from the fungus Daldinia clavata were collected by use of a closed-loop stripping apparatus and analysed by GC-MS. A few compounds were readily identified by comparison of measured to library mass spectra and of retention indices to published data, while for other compounds a synthesis of references was required. For one of the main compounds, 5-hydroxy-4,6-dimethyloctan-3-one, the relative and absolute configuration was determined by synthesis of all eight stereoisomers and gas chromatographic analysis using a homochiral stationary phase. Another identified new natural product is 6-nonyl-2H-pyran-2-one. The antimicrobial and cytotoxic effects of the synthetic volatiles are also reported.
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Beilstein J Org Chem. 2018 Jan 12;14:135-147. doi: 10.3762/bjoc.14.9. eCollection 2018.
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en
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1860-5397
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Attribution-NonCommercial-ShareAlike 4.0 International