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LANGMUIR-BLODGETT-FILMS OF PHTHALOCYANINATO-POLYSILOXANE-POLYMERS AS A NOVEL TYPE OF CHEMFET-MEMBRANE
Vogel, A. ; Hoffmann, B. ; Sauer, Th. ; Wegner, G.
Vogel, A.
Hoffmann, B.
Sauer, Th.
Wegner, G.
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Issue Date
1989
Submitted date
2024-01-16
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Abstract
The formation of Langmuir-Blodgett films (LB-films) by substituted phthalocyaninato-polysiloxane-polymers is a new principle in this field of research since this material lacks the amphiphilic nature which has been thought of being the basic requirement for successful LB film production. Multilayers of the polymere were built up and successfully transferred to Si/SiO, -substrates. They formed macroscopically well-ordered, thermally and chemically stable films. In an Electrolyte/Insulator/Silicon-configuration (EIS-system) they were tested for their usability as CHEMFET-membranes. A long-time stability of at least 3 months in contact with buffer solutions was observed. A pH-sensitivity of 40-50 mV/pH was found with a permanent but irregular baseline drift probably due to ionic migration in the membrane.
Citation
Biosensors : applications in medicine, environmental protection and process control, 347 - 356
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Type
Book chapter
conference paper
conference paper
Language
en
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Series/Report no.
GBF monographs ; Volume 13
ISSN
0930-4320
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ISBN
3527280324
0895739550
0895739550
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Attribution-NonCommercial-ShareAlike 4.0 International
