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dc.contributor.authorWiebach, Vincent
dc.contributor.authorSurup, Frank
dc.contributor.authorKuhnert, Eric
dc.contributor.authorStadler, Marc
dc.date.accessioned2020-02-05T09:58:18Z
dc.date.available2020-02-05T09:58:18Z
dc.date.issued2016-07-01
dc.identifier.citationNat Prod Commun. 2016 Jul;11(7):909-912.en_US
dc.identifier.issn1934-578X
dc.identifier.pmid30452160
dc.identifier.doi10.1177/1934578X1601100711
dc.identifier.urihttp://hdl.handle.net/10033/622118
dc.description.abstractHerein we report the isolation from Hypoxylon rickii of a new sesquiterpenoid (1) with a caryophyllane skeleton. The planar structure of 1 was elucidat ed by NMR and HRMS data as the 1,12-dihydro-l-hydroxyl derivative of caryophyllenol-I, for which we propose the name rickicaryophyllane A. Its relative stereochemistry was assigned with a series of ID NOESY experiments, while the IR,2S,5R,9R absolute configuration was demonstrated by Mosher's analysis. Besides, we isolated 3-(hydroxymethyl)-1,1,3,5-tetramethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one (2) as a new 10-norbotryane derivative and the known metabolite orcacetophenone (3).en_US
dc.language.isoenen_US
dc.publisherSAGE Publicationsen_US
dc.rightsAttribution-NonCommercial-ShareAlike 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/4.0/*
dc.subjectXylariaceaeen_US
dc.subjectXylarialesen_US
dc.subjectSecondary metabolitesen_US
dc.subjectStructure elucidationen_US
dc.subjectSesquiterpenesen_US
dc.titleRickicaryophyllane A, a Caryophyllane from the Ascomyceteous Fungus Hypoxylon rickii and a 10-Norbotryane Congener.en_US
dc.typeArticleen_US
dc.contributor.departmentHZI,Helmholtz-Zentrum für Infektionsforschung GmbH, Inhoffenstr. 7,38124 Braunschweig, Germany.en_US
dc.identifier.journalNatural product communicationsen_US
refterms.dateFOA2020-02-05T09:58:19Z
dc.source.journaltitleNatural product communications


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